6533b7d7fe1ef96bd1268ffb
RESEARCH PRODUCT
The inherent structural instability: concentration-dependent transformation of pyrogallarene to pyrogallarene lactones.
Elina KaleniusKari RissanenJanne JänisN. Kodiah Beyehsubject
ChemistryMetals and AlloysKeteneGeneral ChemistryInstabilityCatalysisTransformation (music)Surfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsConcentration dependentchemistry.chemical_compoundComputational chemistryMaterials ChemistryCeramics and CompositesMoleculeOrganic chemistrydescription
Pyrogallarene shows concentration-dependent instability in dilute solutions resulting in elimination of two ketene molecules and formation of pyrogallarene lactones. This unexpected phenomenon, which is not observed with resorcinarenes, highlights the significance of the four hydroxyl groups at 2-position for the molecular characteristics of pyrogallarenes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-01-15 | Chemical communications (Cambridge, England) |