6533b7d8fe1ef96bd126a12d

RESEARCH PRODUCT

Non-radiative recombination centres in catalyst-free ZnO nanorods grown by atmospheric-metal organic chemical vapour deposition

V. SalletD.n. MontenegroOmar S. MartinezV. HortelanoJuan JiménezM.c. Martínez-tomásVicente Muñoz-sanjosé

subject

Materials scienceAcoustics and Ultrasonicsbusiness.industryAnalytical chemistrychemistry.chemical_elementCathodoluminescenceZincChemical vapor depositionCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisMetalsymbols.namesakechemistryvisual_artsymbolsvisual_art.visual_art_mediumOptoelectronicsNanorodbusinessRaman spectroscopyNon-radiative recombination

description

We have investigated the cathodoluminescence (CL) emission and the Raman spectra along individual ZnO nanorods grown by a catalyst-free method. The spatial correlation between the CL emission and the defect related Raman modes permits establishing a correspondence between the non-radiative recombination centres (NRRCs) and the defects responsible for the 275 cm−1 Raman band. According to this relation, the NRRCs in these nanorods are tentatively associated with complexes of zinc interstitials.

https://doi.org/10.1088/0022-3727/46/23/235302