6533b7d8fe1ef96bd126a355

RESEARCH PRODUCT

Structural reorganization in a hydrogen-bonded organic framework

Carlos Martí-gastaldoNatalia M. PadialJavier Castells-gil

subject

Hydrogen010405 organic chemistryChemistrySupramolecular chemistryQuímica organometàl·licaRecrystallization (metallurgy)chemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesChemical engineeringMaterials ChemistryCristallsDissolution

description

Self-recognition of 3,3′,5,5′-azobenzenetetracarboxylic acid drives the formation of a grid-like anionic hydrogen-bonded framework with channels occupied by organic cations. This supramolecular solid is capable of reorganizing its connectivity in the presence of specific guests into a different crystalline architecture by sequential dissolution and recrystallization.

10.1039/c8nj02738bhttps://doi.org/10.1039/C8NJ02738B