Zum Mechanismus der Polymerkristallisation

6533b7d9fe1ef96bd126caa8

RESEARCH PRODUCT

Zum Mechanismus der Polymerkristallisation

V. Mathot R. Hosemann G. Urban T. Engelke H. G. Zachmann Gert Strobl H. Meier

subject

Colloid and Surface Chemistry Polymers and Plastics Chemistry Materials Chemistry Physical and Theoretical Chemistry Humanities

description

Auf der Grundlage der Ergebnisse von Rontgenkleinwinkel-Streuexperimenten und elektroenenmikroskopischen Untersuchungen an verzweigtem Polyethylen wird ein neues Modell zum Ablauf des partiellen Kristallisierens und Schmelzens entwickelt. Im Modell wird der Aufbau der Lamellarstruktur als sukzessive „Einschubkristallisation“ beschrieben, die durch die Konzentration an nichtkristallisierfahigen Einheiten in den amorphen Bereichen gesteuert wird. Die Kinetik der Einschubkristallisation last sich durch dilatometrische Experimente verfolgen. Aus vergleichenden Rontgenkleinwinkel- und Ramanstreuexperimenten kann auf eine Anreicherung der Cobausteine an den Lamellenoberflachen geschlossen werden.

year	journal	country	edition	language
1982-04-01	Colloid and Polymer Science

https://doi.org/10.1007/bf01448145

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