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RESEARCH PRODUCT
Diene/olefin/polar monomer copolymerisation: unprecedented functional polymers from a rare earth catalyst
Fanny BonnetDenise Barbier-baudryAlain DormondMarc Visseauxsubject
chemistry.chemical_classificationOlefin fiberMaterials sciencePolymers and PlasticsDieneOrganic ChemistryPolymerchemistry.chemical_compoundMonomerchemistryPolymer chemistryMaterials ChemistryCopolymerOrganic chemistryFunctional polymersCaprolactoneIsoprenedescription
An ansasamarocene allyl system is an efficient initiator which polymerises 1,3-dienes, copolymerises dienes and long-chain α-olefins or α,ω-dienes to give functionalisable polymers. It also polymerises caprolactone and allows the controlled diblock copolymerisation of isoprene or isoprene/ α-olefin copolymer and caprolactone.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-01-01 | Polymer International |