6533b7dafe1ef96bd126e321
RESEARCH PRODUCT
Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands.
Sandip BhowmikMatti HaukkaRajendhraprasad TatikondaKari RissanenMassimo Camettisubject
Metal chlorideAqueous solutiongelation capabilitiesligands02 engineering and technologyligandit010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistrymetallogel formationPolymer chemistryOrganic chemistryTerpyridine0210 nano-technologyDMSOta116description
Terpyridine based ligands 1 and 2, decorated with a C8F17 perfluorinated tag, are able to form stable thermoreversible gels in the presence of several d-block metal chloride salts. The gel systems obtained have been characterized by NMR, X-ray diffraction, electron microscopies and Tgel experiments in order to gain insights into the observed different behaviour of the two similar ligands, also in terms of the effect of additional common anionic species. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-07-28 | Dalton transactions (Cambridge, England : 2003) |