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RESEARCH PRODUCT
Proposal of Isobutyl Alcohol as Entrainer To Separate Mixtures Formed by Ethanol and Water and 1-Propanol and Water
Estela LladosaSonia LorasJuan B. MontónJordi Pla-francosubject
EthanolChromatographyGeneral Chemical EngineeringAnalytical chemistry02 engineering and technologyGeneral Chemistry021001 nanoscience & nanotechnologymedicine.diseaselaw.inventionSolventchemistry.chemical_compound1-Propanol020401 chemical engineeringchemistrylawAzeotropemedicineIsobaric processDehydration0204 chemical engineering0210 nano-technologyTernary operationDistillationdescription
Isobutyl alcohol (IBA) has been proposed as a solvent to carry out the dehydration of ethanol and 1-propanol by means of a nonconventional distillation process. In this way, isobaric vapor–liquid equilibrium (VLE) and vapor–liquid–liquid equilibrium (VLLE) data at atmospheric pressure have been obtained for the ternary systems ethanol (1a) + water (2) + IBA (3) and 1-propanol (1b) + water (2) + IBA (3). Then, these data have been correlated to obtain a set of parameters capable of estimating VLE and VLLE. According to the results achieved, distillation sequences to separate water and ethanol or 1-propanol have been proposed. Finally, a study about the minimum amount of entrainer required to break the azeotrope of the mixture ethanol/1-propanol + water is carried out.
year | journal | country | edition | language |
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2017-05-24 | Journal of Chemical & Engineering Data |