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RESEARCH PRODUCT

First High-Resolution Raman Spectrum and Analysis of the ν5 Bending Fundamental of SF6

Vincent BoudonDionisio Bermejo

subject

Materials scienceHigh resolutionBendingMolecular spectroscopyAtomic and Molecular Physics and OpticsSulfur hexafluoridesymbols.namesakechemistry.chemical_compoundNuclear magnetic resonancechemistrysymbolsMoleculePhysical and Theoretical ChemistryAtomic physicsRaman spectroscopySpectroscopy

description

Abstract The high-resolution Raman spectrum of the Q , R , and S branches of the ν 5 bending fundamental of SF 6 has been recorded at a temperature of 195 K (dry ice) and a pressure of 39 mbar. This is the first study ever performed of a ν 5 band of an XY 6 molecule. It has been analyzed thanks to the HTDS software ( http://www.u-bourgogne.fr/LPUB/shTDS.html ) developed in Dijon. This contribution should be of help in understanding the role hot bands in the strong absorbing ν 3 region.

yearjournalcountryeditionlanguage
2002-06-01Journal of Molecular Spectroscopy
https://doi.org/10.1006/jmsp.2002.8552