6533b7dbfe1ef96bd12715df
RESEARCH PRODUCT
Lanthanide molecular oxohydroxides: Synthesis and characterisation of [Y4(μ4-O)(μ-OEt)2(μ,η2-AAA)2(η2-AAA)3]2(μ3-OH)4(μ3-OEt)2 (HAAA = allylacetatoacetate)
Liliane G. Hubert-pfalzgrafStéphane DanielePhilippe RichardAnne BrethonLauren C. Cauro-gametsubject
LanthanideInorganic chemistrychemistry.chemical_element02 engineering and technologyAlkoxides010402 general chemistry01 natural sciences"Polymerizable ligands"StyreneInorganic Chemistrychemistry.chemical_compoundPolymer chemistryMaterials ChemistryYttriumPhysical and Theoretical ChemistryPolymerizable ligands"Alkoxides"Doping"X-ray structure"Yttrium[CHIM.CATA]Chemical Sciences/Catalysis021001 nanoscience & nanotechnology[SDE.ES]Environmental Sciences/Environmental and Society0104 chemical scienceschemistryPolystyreneX-ray structure0210 nano-technology"Yttrium"Derivative (chemistry)Stoichiometrydescription
International audience; The reaction between Y5O(OPri)13 and allylacetatoacetate or 2-(methacryloyloxy)ethyl acetatoacetate in 1:5 stoichiometry afforded octanuclear oxohydroxo species. Structural characterization was achieved for the allylacetatoacetate derivative homo and copolymerisation reactions with styrene were evaluated for doping of polystyrene. Hydoxo species, Y4(OH)2(AAA)10, where also obtained by reacting Y[N(SiMe3)]3 and HAAA.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-02-01 |