6533b7dcfe1ef96bd1272c80
RESEARCH PRODUCT
High temperature spin crossover in [Fe(pyrazine){Ag(CN) 2 } 2 ] and its solvate
Wolfgang TremelIl'ya A. Gural'skiyIl'ya A. Gural'skiyIgor O. FritskyVadim KsenofontovBohdan O. GolubSergii I. ShylinSergii I. Shylinsubject
Pyrazine010405 organic chemistryTransition temperatureGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesCatalysis0104 chemical sciences3. Good healthCrystallographychemistry.chemical_compoundchemistrySpin crossoverMaterials ChemistryMoleculeAcetonitriledescription
A high temperature spin crossover (Tup = 367 K) was detected in a metal–organic framework [Fe(pz){Ag(CN)2}2]·MeCN (pz = pyrazine). Upon heating, this solvate released acetonitrile guest molecules, which slightly shifted the transition temperature of the complex (Tup = 370 K and Tdown = 356 K).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-01-01 | New Journal of Chemistry |