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RESEARCH PRODUCT
Quadruply-bonded dimolybdenum compounds: Reactivity towards TCNE. Structural evidences for the 1-D polymer [Mo2(O2 CCF3)4(TCNE)]∞
Jean-michel KerbaolYves Le MestJean Pala SalaBenoît Le GallEstelle VigierMarek M. KubickiFrançoise Conansubject
chemical reactionReaction mechanismStereochemistryCoordination polymerGeneral Chemical EngineeringpolymerCrystal structureTetracyanoethylene010402 general chemistryligand01 natural scienceschemistry.chemical_compoundmolybdenumelectrochemical analysisMoietyMoleculetoluene[CHIM]Chemical SciencesReactivity (chemistry)electron transportchemical bondinfrared spectroscopychemical binding010405 organic chemistryChemistryarticleBridging ligandGeneral Chemistrycarbon nuclear magnetic resonance0104 chemical sciencesCrystallographychemical analysispolymerizationchemical structureorganometallic compounddescription
cited By 3; International audience; Reaction of [Mo2(O2CR)4] (R = CF 3, 1) with TCNE in toluene affords the new compound [Mo2(O2CCF3)4 (TCNE)·6H5CH3 (2). The structure of 2 is built on [Mo2(O2 CCF3)4] fragments having the usual paddlewheel structure of 1 (Mo-Mo 2.1117(8) Å) and TCNE units. Each polynitrile moiety acts as a bridging ligand between two Mo2 fragments (Mo-N 2.875(4) Å) affording 1-D polymeric chains crossing in the crystal; the toluene molecules occupy the cavities between the chains. 13C NMR, IR and electrochemical data clearly show that formation of 2 does not involve electron density transfer from dimolybdenum fragment to the TCNE unit, which remains in 2 in its neutral state. © 2004 Académie des sciences. Published by Elsevier SAS. All rights reserved.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-06-01 |