6533b7defe1ef96bd1275b3d

RESEARCH PRODUCT

Die aufschlußfreie Bestimmung von Schwermetallen (Zn, Cd, Pb, Cu) in Getränken (Wein) durch inverse Voltammetrie in einer Durchflußzelle

Rolf NeebFaramarz Wahdat

subject

chemistrySupporting electrolyteWet digestionClinical BiochemistryAnalytical chemistrychemistry.chemical_elementGeneral Materials ScienceGeneral MedicineVoltammetryAnalytical ChemistryMercury (element)

description

Digestion-free determination of trace-metals (Zn, Cd, Pb, Cu) in beverages by inverse voltammetry in a flow-through cell equipped with a mercury film-electrode is described. Optimal enrichment potentials are obtained by inspection of the pseudopolarograms of the elements in the original diluted sample solution. After the deposition step in the untreated sample solution stripping is effected in a proper supporting electrolyte after medium exchange. Values obtained by this techniques with various samples compare well with those obtained by usual procedures including wet digestion of the samples.

https://doi.org/10.1007/bf00469813