6533b7defe1ef96bd1275bd4

RESEARCH PRODUCT

Microwave Fourier Transform Spectroscopy of Rovibrational Transitions in the ν 2 /ν 4 Dyads of Methane- 12 C and - 13 C

M. OldaniAlfred BauderJ.c. HilicoJean-paul ChampionMichel Loete

subject

Materials scienceSpectrometerGeneral Physics and AstronomyRotational–vibrational spectroscopySpectral lineFourier transform spectroscopyMethanechemistry.chemical_compoundNuclear magnetic resonancechemistryMoleculeAtomic physicsMicrowaveLine (formation)

description

The ν2/ν4 dyad-dyad spectra of 12CH4 and 13CH4 molecules in the (8÷20) GHz region have been predicted including line strengths. All transitions with γmax > 810-12 cm-1 have been observed directly using a MWFT spectrometer: six F-type transitions for 12CH4 and nine for 13CH4.

https://doi.org/10.1209/0295-5075/4/1/005