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RESEARCH PRODUCT
Confined growth of cyanide-based magnets in two dimensions
Eugenio CoronadoAntonio RiberaCarlos Martí-gastaldoEfrén Navarro-moratallasubject
Molecular magnetsCyanideIntercalation (chemistry)Inorganic chemistry02 engineering and technologyequipment and supplies010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryChemical physicsMagnetDiamagnetismPhysical and Theoretical Chemistry0210 nano-technologyhuman activitiesdescription
Herein we report the first hybrid magnetic material resulting from the intercalation of a cyanide-based molecular magnet into a solid-state layered host. More specifically, the use of a diamagnetic cationic Zn(II)-Al(lII) layered double hydroxide host allows for the formation of an anionic two-dimensional ferromagnetic Ni(II)-Cr(III) Prussian Blue analogue, from the templated assembly of its ionic molecular components in the confined interlamellar space offered by the inorganic host.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-01-08 | Inorganic Chemistry |