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RESEARCH PRODUCT

Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition

Lluis M. GuiaM. Carmen Martínez-tomásSaid HassaniVincent SalletVicente Muñoz-sanjosé

subject

Materials scienceScanning electron microscopeAlloyAnalytical chemistryQuímica organometàl·lica02 engineering and technologyChemical vapor depositionengineering.material01 natural sciencesLattice constantPhase (matter)0103 physical sciencesGeneral Materials ScienceThin filmComputingMilieux_MISCELLANEOUS010302 applied physics[PHYS]Physics [physics]General ChemistryAtmospheric temperature rangeTemperatura021001 nanoscience & nanotechnologyCondensed Matter Physicsengineering0210 nano-technologyTernary operation

description

II-VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal-organic precursors content, a change from Mg1-xCdxO (Mg-rich phase) to Cd1-xMgxO (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron microscopy, a structural and morphological study of the samples has been carried out. In addition, the composition of the alloy has been measured by using energy dispersive X-ray analysis, and the behavior of the lattice parameter as a function of Cd content has been studied.

10.1021/acs.cgd.7b00989https://hal.archives-ouvertes.fr/hal-02972562