0000000000430002

AUTHOR

M. Carmen Martínez-tomás

showing 7 related works from this author

Effect of Growth Temperature on the Structural and Morphological Properties of MgCdO Thin Films Grown by Metal Organic Chemical Vapor Deposition

2017

II-VI oxides ternary alloys have attracted considerable interest of the scientific community due to the possibility of modulating their interesting optoelectronic properties. Despite this interest, MgCdO has been poorly studied. In this work, by using the metal organic chemical vapor deposition method at low pressure, we have analyzed the synthesis of thin films of this alloy. Thus, for a fixed metal-organic precursors content, a change from Mg1-xCdxO (Mg-rich phase) to Cd1-xMgxO (Cd-rich phase) has been induced when decreasing the growth temperature. The temperature range where both phases coexist has been particularly analyzed. Using X-ray diffraction analysis and scanning electron micros…

Materials scienceScanning electron microscopeAlloyAnalytical chemistryQuímica organometàl·lica02 engineering and technologyChemical vapor depositionengineering.material01 natural sciencesLattice constantPhase (matter)0103 physical sciencesGeneral Materials ScienceThin filmComputingMilieux_MISCELLANEOUS010302 applied physics[PHYS]Physics [physics]General ChemistryAtmospheric temperature rangeTemperatura021001 nanoscience & nanotechnologyCondensed Matter Physicsengineering0210 nano-technologyTernary operation
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One-step growth of isolated CdO nanoparticles on r-sapphire substrates by using the spray pyrolysis methodology

2014

In spite of the remarkable properties of CdO, there are only a few reports on CdO nanostructures, especially on isolated NPs. In this paper, we analyze the growth of isolated CdO nanoparticles (NPs) on 0.5° miscut r-sapphire substrates by using the spray pyrolysis methodology in its classical configuration. A systematic study has been performed to optimize the growth parameters such as precursor concentration, growth time, spray rate and growth temperature to obtain CdO NPs (size: 6–10 nm to 35–100 nm depending on the growth conditions). The study shows the control over the size and density of the CdO nanoparticles that can be achieved by adjusting the growth parameters. The CdO nanoparticl…

NanostructureMaterials scienceChemical engineeringX-ray photoelectron spectroscopyTransmission electron microscopyGeneral Chemical EngineeringNucleationNanoparticleNanotechnologyGeneral ChemistrySubstrate (electronics)CrystalliteSelected area diffractionRSC Advances
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Growth and characterization of self-assembled Cd1−xMgxO (0 ≤ x ≤ 1) nanoparticles on r-sapphire substrates

2014

In this work, the growth of isolated Cd1−xMgxO nanoparticles on r-sapphire substrates is extended to the entire range of Mg content (0 ≤ x ≤ 1) using the spray pyrolysis method. The sizes of the Cd1−xMgxO nanoparticles were in the ranges 4–6 nm and 15–30 nm (with a nanoparticle density of 1010 cm−2). The composition of the nanoparticles was determined using transmission electron microscopy energy dispersive X-ray analysis (TEM-EDAX), while the compound formation was confirmed using X-ray photoelectron spectroscopy. A systematic decrease in the a lattice parameter of Cd1−xMgxO on increasing the Mg content substantiated the successful incorporation of Mg2+ ions into the cubic CdO lattice. Sin…

DiffractionLattice constantMaterials scienceX-ray photoelectron spectroscopyTransmission electron microscopySapphireAnalytical chemistryNanoparticleGeneral Materials ScienceGeneral ChemistrySelected area diffractionCondensed Matter PhysicsIonCrystEngComm
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Hybrid multiple diffraction in semipolar wurtzite materials: (\bf 01\overline{1}2)-oriented ZnMgO/ZnO heterostructures as an illustration

2017

X-ray diffraction has been widely used to characterize the structural properties (strain and structural quality) of semiconductor heterostructures. This work employs hybrid multiple diffraction to analyzer-oriented Zn1−xMgxO layers grown by molecular beam epitaxy on ZnO substrates. In such a low-symmetry material system, additional features appear in symmetric reflection scans, which are described as arising from hybrid multiple diffraction. First, the Bragg conditions necessary for these high-order processes to occur are introduced and applied to explain all the observed satellite reflections, identify the planes that contribute and computea priorithe angles at which they are observed. Fur…

[PHYS]Physics [physics]010302 applied physicsDiffractionMaterials sciencebusiness.industryX-ray multiple diffractionHeterojunction02 engineering and technologyMultiple diffraction021001 nanoscience & nanotechnology01 natural sciencesGeneral Biochemistry Genetics and Molecular BiologyReciprocal latticehybrid peaksLattice (order)0103 physical sciencesOptoelectronicsA priori and a posteriori0210 nano-technologybusinessWurtzite crystal structureMolecular beam epitaxyJournal of Applied Crystallography
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Self-Assembled Zinc Oxide Quantum Dots Using Spray Pyrolysis Methodology

2011

Self-assembled ZnO quantum dots (QDs) have been obtained on different substrates by using the atmospheric spray pyrolysis methodology under well-defined growth conditions. The evolution of size and...

Materials scienceCondensed Matter::OtherInorganic chemistrychemistry.chemical_elementGeneral ChemistryZincCondensed Matter::Mesoscopic Systems and Quantum Hall EffectCondensed Matter PhysicsSpray pyrolysisSelf assembledCondensed Matter::Materials SciencechemistryChemical engineeringQuantum dotPhysics::Atomic and Molecular ClustersGeneral Materials ScienceCrystal Growth & Design
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Growth and characterization of Mg 1‐x Cd x O thin films

2016

In this paper, we study the growth of thin films of the Mg1–xCdxO alloy in the Mg-rich range of compositions by using the metal organic chemical vapour deposition (MOCVD) method at low pressure. X-ray diffraction (XRD) has been used to analyse the compound formation and the progressive incorporation of Cd2+ ions into the cubic MgO lattice. Both, layers with a single-cubic phase of Mg1–xCdxO and layers with a phase separation, where Cd1–xMgxO and Mg1–xCdxO coexist, have been studied. Finally, a morphological study of the layers has been carried out by using scanning electron microscopy (SEM) and the layers' composition has been measured by energy dispersive X-ray analysis (EDX). (© 2016 WILE…

DiffractionMaterials scienceScanning electron microscopeAlloyAnalytical chemistry02 engineering and technologyChemical vapor depositionengineering.material010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciences0104 chemical sciencesMetalvisual_artPhase (matter)visual_art.visual_art_mediumengineeringMetalorganic vapour phase epitaxyThin film0210 nano-technologyphysica status solidi c
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Growth of tin oxide thin films composed of nanoparticles on hydrophilic and hydrophobic glass substrates by spray pyrolysis technique

2015

Abstract In this paper, we have demonstrated the growth of tin oxide (SnO 2 ) thin films composed of nanoparticles on hydrophobic (siliconized) and hydrophilic (non-siliconized) glass substrates by using the spray pyrolysis technique. X-ray diffraction (XRD) analysis confirmed the formation of SnO 2 thin films with tetragonal rutile-phase structure. Average particle size of nanoparticles was determined to be in the range of 3–4 nm measured from the front view images obtained by a field emission gun scanning electron microscope (FESEM), while the size of nanoparticle clusters, when present, were in the range of 11–20 nm. Surface morphology of SnO 2 films grown over hydrophobic substrates rev…

PhotoluminescenceMaterials scienceBand gapScanning electron microscopeAnalytical chemistryGeneral Physics and AstronomyNanoparticleSurfaces and InterfacesGeneral ChemistryCondensed Matter PhysicsTin oxideSurfaces Coatings and FilmsParticle sizeThin filmField emission gunApplied Surface Science
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