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RESEARCH PRODUCT
Organotin(IV) chloride complexes with phosphocholine and dimyristoyl-L-?-phosphatidylcholine
E. V. GrigorievN. S. YashinaLorenzo PelleritoClaudia PelleritoValery S. Petrosyansubject
ChemistryStereochemistryHexacoordinatechemistry.chemical_elementGeneral ChemistryMedicinal chemistryChemical synthesisInorganic ChemistryTrigonal bipyramidal molecular geometrychemistry.chemical_compoundOctahedronMössbauer spectroscopyPhosphodiester bondTinPhosphocholinedescription
Several complexes of R n SnCl 4-n (R = Me, Ph, n = 1-3; R = nBu, n = 2, 3) with phosphocholine and dimyristoyl-L-α-phosphatidylcholine (phospholipid) have been synthesized and characterized by means of Mossbauer spectroscopy and NMR. Triorganotin chlorides form complexes of (R 3 SnCl) 2 .L stoichiometry with a trigonal bipyramidal pentacoordinate tin environment, while the others form 1:1 complexes with an octahedral hexacoordinate tin environment, with the ligands coordinating through anionic phosphodiester moieties in all cases.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-01-01 | Applied Organometallic Chemistry |