6533b81ffe1ef96bd12786a9

RESEARCH PRODUCT

Complexes of organometallic compounds

Francesca Di BiancaEleonora RivarolaGiuseppina Faraglia

subject

chemistry.chemical_classificationBase (chemistry)InfraredHydrogen bondOrganic ChemistryInorganic chemistryIntermolecular forceSolid-stateHalidechemistry.chemical_elementInfrared spectroscopyGeneral MedicineBiochemistryBismuthInorganic ChemistryOctahedronchemistryAtomPolymer chemistryMaterials ChemistryThalliumChelationPhysical and Theoretical ChemistryGroup 2 organometallic chemistry

description

Abstract The novel organobismuth(V) derivatives Ph 3 BiCl(Ox) and Ph 3 BiBr(Ox) (Ox − = 8-quinolinate) have been synthesized, and their configuration investigated in the solid state and in solution. The complexes are assumed to be octahedral in the solid, with Ox − acting as a chelating base and the halide atoms coordinating to bismuth. Tentative assignments of infrared bands in the 300–80 cm −1 region to BiHal and other skeletal modes are proposed. The main effect of solvents appears to be the weakening and breaking of BiN-bonds.

yearjournalcountryeditionlanguage
1972-05-01Bioinorganic Chemistry
https://doi.org/10.1016/s0006-3061(00)80301-4