Activation of the Cyano Group at Imidazole via Copper Stimulated Alcoholysis

6533b81ffe1ef96bd1278814

RESEARCH PRODUCT

Activation of the Cyano Group at Imidazole via Copper Stimulated Alcoholysis

Igor O. Koshevoy Sirpa Jääskeläinen Rezeda Gayfullina Pipsa Hirva

subject

Steric effects Denticity chemistry.chemical_element Infrared spectroscopy 010402 general chemistry 01 natural sciences Medicinal chemistry DFT imidazole Inorganic Chemistry chemistry.chemical_compound QTAIM (Quantum Theory of Atoms in Molecules)lcsh:Inorganic chemistry Imidazole cyano structural analysis copper complex 010405 organic chemistry Ligand alcoholysis epäorgaaninen kemia Copper lcsh:QD146-197 0104 chemical sciences Carboximidate chemistry Alkoxy group

description

Reactions of 4,5-dicyano-1-methylimidazole with CuX2 (X = Cl, Br) in alcohol solvents (ethanol and methanol) resulted in the formation of Cu(II) carboximidate complexes [CuCl2(5- cyano-4-C(OEt)N-1-methylimidazole)(EtOH)] (1), [Cu2(&micro

year	journal	country	edition	language
2019-07-01	Inorganics

10.3390/inorganics7070087 http://dx.doi.org/10.3390/inorganics7070087

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