Stable Methylene- and Oxo-Bridged Monocyclopentadienyl Titanium Compounds. Molecular Structure of {Ti[μ-(η5-C5Me4SiMe2-O)]Me}2(μ-CH2)

6533b820fe1ef96bd127a2e4

RESEARCH PRODUCT

Stable Methylene- and Oxo-Bridged Monocyclopentadienyl Titanium Compounds. Molecular Structure of {Ti[μ-(η5-C5Me4SiMe2-O)]Me}2(μ-CH2)

Gerardo Jiménez Carmen Ramírez De Arellano Olga Buitrago Tomas Cuenca

subject

Inorganic Chemistry chemistry.chemical_compound Chemistry Organic Chemistry Polymer chemistry Inorganic chemistry Thermal decomposition Molecule chemistry.chemical_element Physical and Theoretical Chemistry Methylene Methane Titanium

description

Thermolysis of {Ti[μ-(η5-C5Me4SiMe2-O)]Me2}2 affords the methylene-bridged titanium compound {Ti[μ-(η5-C5Me4SiMe2-O)]Me}2(μ-CH2), concurrent with the evolution of methane, the first example of a fu...

year	journal	country	edition	language
2004-10-27	Organometallics

https://doi.org/10.1021/om0495426

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