6533b821fe1ef96bd127c3a8

RESEARCH PRODUCT

Gamma radiation of EVA-AA/MMA swollen systems to obtain mechanically improved blends

Giuseppe SpadaroAntonino ValenzaClelia DispenzaAnnamaria Visco

subject

chemistry.chemical_classificationThermoplasticMaterials sciencePolymers and PlasticsOrganic Chemistrytechnology industry and agricultureBlends gamma radiation rubber-glassy thermoplastic componentsCondensed Matter Physicschemistry.chemical_compoundSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiMonomerchemistryPhase (matter)Ultimate tensile strengthMaterials ChemistrymedicineSettore CHIM/07 - Fondamenti Chimici Delle TecnologiePolymer blendSwellingmedicine.symptomComposite materialIonomerAcrylic acid

description

In this work a "new" way to obtain "compatibilised" blends of rubber-glassy thermoplastic components is presented. Polyethylen-vinyl acetate acrylic acid terpolymer is swollen by methylmetacrylate and the system is irradiated through gamma rays in order to induce polymerisation of the monomer. Solubility and dynamic mechanical tests indicate the formation of a two phase system, even though in presence of strong interactions between the two components. Mechanical tensile behaviour is that of a ductile material with appreciable modulus values.

https://doi.org/10.1002/1521-3900(200203)180:1<33::aid-masy33>3.0.co;2-0