The solution behavior of dopamine in the presence of mono and divalent cations: A thermodynamic investigation in different experimental conditions

6533b822fe1ef96bd127d7d7

RESEARCH PRODUCT

The solution behavior of dopamine in the presence of mono and divalent cations: A thermodynamic investigation in different experimental conditions

Rosalia Maria Cigala Alberto Pettignano Anna Irto Antonio Gigliuto Francesco Crea Concetta De Stefano Maria Rosa Felice Demetrio Milea Stefano Materazzi

subject

Models Molecular Cations Divalent Dopamine Potentiometric titration Enthalpy Ionic bonding Biochemistry Microbiology Article Divalent chemistry.chemical_compound Metal complexes TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY Settore CHIM/01 - Chimica Analitica Stability constants Molecular Biology chemistry.chemical_classification Catechol; Chemical speciation; Metal complexes; Sequestration; Stability constants Ligand Hydrolysis Osmolar Concentration Temperature Sequestration Hydrogen-Ion Concentration QR1-502 Solutions Kinetics chemistry Specific ion interaction theory Ionic strength Thermogravimetry Catechol Physical chemistry Thermodynamics Chemical speciation Ethylamine

description

The interactions of dopamine [2-(3,4-Dihydroxyphenyl)ethylamine, (Dop-)] with methylmercury(II) (CH3Hg+), magnesium(II), calcium(II), and tin(II) were studied in NaCl(aq) at different ionic strengths and temperatures. Different speciation models were obtained, mainly characterized by mononuclear species. Only for Sn2+ we observed the formation of binuclear complexes (M2L2 and M2LOH (charge omitted for simplicity)

year	journal	country	edition	language
2021-09-01

10.3390/biom11091312 http://hdl.handle.net/11570/3210723

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