6533b823fe1ef96bd127ed2d

RESEARCH PRODUCT

Harnessing Molecular Fluorophores in the Carbon Dots Matrix: The Case of Safranin O

Manuela MeloniLuigi StagiDavide SannaSebastiano GarroniLaura CalvilloAngela TerracinaMarco CannasFabrizio MessinaCarlo Maria CarbonaroPlinio InnocenziLuca Malfatti

subject

safranincarbon dots; safranin; phosphors; nanoparticlesGeneral Chemical Engineeringcarbon dotsSettore FIS/01 - Fisica Sperimentalecarbon dots; nanoparticles; phosphors; safraninGeneral Materials Sciencenanoparticlesphosphors

description

The origin of fluorescence in carbon dots (C-dots) is still a puzzling phenomenon. The emission is, in most of the cases, due to molecular fluorophores formed in situ during the synthesis. The carbonization during C-dots processing does not allow, however, a fine control of the properties and makes finding the source of the fluorescence a challenging task. In this work, we present a strategy to embed a pre-formed fluorescent molecule, safranin O dye, into an amorphous carbonaceous dot obtained by citric acid carbonization. The dye is introduced in the melted solution of citric acid and after pyrolysis remains incorporated in a carbonaceous matrix to form red-emitting C-dots that are strongly resistant to photobleaching. Embedding dyes in amorphous C-dots represents an alternative method to optimize the emission in the whole visible spectrum.

10.3390/nano12142351https://hdl.handle.net/10447/579993