6533b823fe1ef96bd127ed64
RESEARCH PRODUCT
Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules
Kari RissanenFangfang PanN. Kodiah Beyehsubject
ChemistryGeneral Chemical EngineeringInorganic chemistrydimeric capsulesGeneral ChemistryResorcinarenelaw.inventionguest moleculeschemistry.chemical_compoundlawPolymer chemistryMoleculeMethanolCrystallizationta116anionsTrifluoromethanesulfonatedescription
Crystallization of N-cyclohexyl ammonium resorcinarene triflate from methanol results in a dimeric capsule capable of trapping two triflate anions and two methanol molecules within a 341 A3 cavity while with 1,4-dioxane as a guest it forms a new larger dimeric capsule with volume of 679 A3 encapsulating four 1,4-dioxane and four water molecules, resulting in packing coefficients of 0.75 and 0.67, respectively.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-01-01 | RSC Advances |