6533b825fe1ef96bd1281d4f

RESEARCH PRODUCT

Die selektive invers-voltammetrische Bestimmung des Antimons in salzsauren Lösungen nach Lösungswechsel in einer einfachen Durchflußzelle

Rolf NeebThomas Frank

subject

ChemistryDetection thresholdStereochemistryClinical Biochemistrychemistry.chemical_elementHydrochloric acidGeneral MedicineCopperAnalytical ChemistryBismuthchemistry.chemical_compoundAntimonyGeneral Materials ScienceNuclear chemistry

description

The selective invers-voltammetric determination of antimony in a simple flow-through cell in hydrochloric acid solutions is described. After double medium exchange for post-electrolysis and inverse-voltammetric determination, the determination of antimony is possible in the presence of a large excess of copper, bismuth and other elements. The limit of determination is 0.2–0.3 ppb Sb, the reproducibility 1.5% (10 ppb Sb).

https://doi.org/10.1007/bf00489158