6533b825fe1ef96bd1281f87

RESEARCH PRODUCT

ORMOSIL thin films: Tuning mechanical properties via a nanochemistry approach

Rosaria CiriminnaDavide TranchidaMario PagliaroGiovanni PalmisanoEric Le Bourhis

subject

PhotonsMaterials sciencebusiness.industryNanochemistryNanotechnologySurfaces and InterfacesCondensed Matter PhysicsOrmosilSilicatePolymerizationtwo-photon polymerizationchemistry.chemical_compoundchemistrySiloxaneElectrochemistryMicroelectronicsGeneral Materials ScienceThin filmbusinessElastic modulusSpectroscopy

description

The mechanical properties (hardness and elastic modulus) of organically modified silicate thin films can be finely tuned by varying the degree of alkylation and thus the fraction of six- and four-membered siloxane rings in the organosilica matrix. This opens the way to large tunability of parameters that are of crucial practical importance for films that are finding increasing application in numerous fields ranging from microelectronics to chemical sensing.

10.1021/la061520whttp://hdl.handle.net/10447/28949