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RESEARCH PRODUCT
Supramolecular Packing Drives Morphological Transitions of Charged Surfactant Micelles
Mikkel ChristensenKen SchäferSigbjørn Løland BoreJürgen GaussMichele CascellaGiuseppe MilanoGregor DiezemannHima Bindu KolliReidar Lundsubject
Materials scienceSupramolecular chemistryIonic bondingNeutron scattering010402 general chemistryMicelle01 natural sciencesCatalysisdimersdetergentSymmetry breakingResearch Articleschemistry.chemical_classificationSmall-angle X-ray scattering010405 organic chemistrymolecular modelingGeneral ChemistryGeneral Medicineself-assemblydimer0104 chemical sciencesCondensed Matter::Soft Condensed MattermicelllechemistrydetergentsChemical physicsMicelllesSelf-assemblyCounterionResearch Articledescription
Abstract The shape and size of self‐assembled structures upon local organization of their molecular building blocks are hard to predict in the presence of long‐range interactions. Combining small‐angle X‐ray/neutron scattering data, theoretical modelling, and computer simulations, sodium dodecyl sulfate (SDS), over a broad range of concentrations and ionic strengths, was investigated. Computer simulations indicate that micellar shape changes are associated with different binding of the counterions. By employing a toy model based on point charges on a surface, and comparing it to experiments and simulations, it is demonstrated that the observed morphological changes are caused by symmetry breaking of the irreducible building blocks, with the formation of transient surfactant dimers mediated by the counterions that promote the stabilization of cylindrical instead of spherical micelles. The present model is of general applicability and can be extended to all systems controlled by the presence of mobile charges.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-01-01 |