6533b825fe1ef96bd1282951
RESEARCH PRODUCT
Do 2-coordinate iodine(I) and silver(I) complexes form Nucleophilic Iodonium Interactions (NIIs) in solution?
Scott WilcoxDaniel SethioJames WardAntonio FronteraRoland LindhKari RissanenMate Erdelyisubject
jodikemialliset yhdisteethopeaNMR halogen bondkidetiededescription
The interaction of a [bis(pyridine)iodine(I)]+ cation with a [bis(pyridine)silver(I)]+ cation, in which an iodonium ion acts as nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between this complexes in solution, it is dominantly the π-π interaction of pyridines peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2022-02-14 |