6533b826fe1ef96bd1284efd

RESEARCH PRODUCT

Differentiation of isomeric cyclic diamides by electron impact mass spectra

Salvatore FotiHelmut RingsdorfIngo LüderwaldGiorgio MontaudoMichael Przybylski

subject

chemistry.chemical_compoundFragmentation (mass spectrometry)chemistryComputational chemistryMetastabilityMass spectrumAnalytical chemistryMolecular MedicineCyclopentaneInstrumentationBiochemistrySpectroscopyElectron ionization

description

The behaviour under electron impact of two series of isomeric cyclopentane- and cyclohexane-1, 2- and -1, 3-dicarboxylic acid dipiperidides was studied. Diagnostic fragmentation pathways were found to differentiate the isomeric diamides. Additional evidence was obtained from the metastable transitions.

https://doi.org/10.1002/oms.1210110608