6533b826fe1ef96bd12852c8
RESEARCH PRODUCT
Suzuki-Miyaura cross-coupling of arenediazonium salts catalyzed by alginate/gellan-stabilized palladium nanoparticles under aerobic conditions in water
Alessandro PrastaroFrancesco PetrucciEugenio CaponettiGiovanni ForteGiancarlo FabriziSandra MorenoPatrizia PaolicelliSandro CacchiAntonella GoggiamaniMaria Antonietta CasadeiAndrea Di GiulioMaria Luisa Saladinosubject
PotassiumInorganic chemistryalginate palladium nanoparticlesPalladium nanoparticleschemistry.chemical_elementPollutionCatalysischemistry.chemical_compoundchemistryMolar ratioEnvironmental ChemistryCoupling (piping)PhosphineSettore CHIM/02 - Chimica FisicaNuclear chemistrydescription
The use of palladium nanoparticles stabilized by natural. beads made of an alginate/gellan mixture in the Suzuki-Miyaura cross-coupling reaction of arenediazonium. tetrafluoroborates with potassium aryltrifluoroborates. (1 : 1 molar ratio) with loading as low as 0.01–0.002. mol% under aerobic, phosphine-, and base-free conditions. in water is described. The catalyst system can be reused. several times without significant loss of activity.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-01-01 |