6533b826fe1ef96bd1285334

RESEARCH PRODUCT

Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework.

Subhadip NeogiSusan SenParimal K. BharadwajKari Rissanen

subject

Chemistryconcomitant transmetalationMetals and AlloysCationic polymerizationSupramolecular chemistryGeneral Chemistrystructural transformationPhotochemistrysingle crystalsCatalysisStructural transformationSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsSolventTransmetalationPolymer chemistryMaterials ChemistryCeramics and CompositesSBusSingle crystalta116

description

A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.

yearjournalcountryeditionlanguage
2015-01-22Chemical communications (Cambridge, England)
10.1039/c4cc09955ahttps://pubmed.ncbi.nlm.nih.gov/25605040