Notiz Über Darstellung und Eigenschaften Einiger Isonitrone (Oxazirane)

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Notiz Über Darstellung und Eigenschaften Einiger Isonitrone (Oxazirane)

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Isonitrone (=Oxazirane) wurden erstmalig von H. Krimm und K. Hamann aus Schiffschen Basen und Persauren dargestellt. Im Gegensatz zu den Nitronen machen Isonitrone Jod bzw. Chlor frei und geben den Sauerstoff quantitativ an Triphenylphosphin ab. Phenyl-N-cyclohexyl-isonitron lagert sich bei 200° in Phenyl-N-cyclohexyl-nitron, letzteres in Gegenwart von Acetylchlorid in N-Cyclohexyl-benzamid um. Isonitrone werden katalytisch unter Aufnahme von 2 Moll. Wasserstoff rasch zu sekundaren Aminen reduziert, wahrend aus den Nitronen in langsamer Reaktion Hydroxylaminderivate entstehen.

year	journal	country	edition	language
1957-10-01	Chemische Berichte

https://doi.org/10.1002/cber.19570901010

PEPhysical Sciences and Engineering
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