6533b827fe1ef96bd1286550
RESEARCH PRODUCT
Synthesis and optoelectronic properties of chemically modified bi-fluorenylidenes
Enrique OrtíRobin Humphry-bakerDamien JolyJoaquín CalboJuan AragóFulvio G. BrunettiJuan Luis DelgadoJuan Luis DelgadoMichael GrätzelNazario MartínNazario MartínJacques-e. MoserShaik M. ZakeeruddinMateusz WielopolskiMagdalena Marszaleksubject
chemistry.chemical_classificationMaterials science010405 organic chemistrybusiness.industryPhotovoltaic systemQuímica orgánicaElectron donorNanotechnologyGeneral ChemistryElectron acceptor010402 general chemistry01 natural sciences0104 chemical scienceschemistry.chemical_compoundchemistryPhotovoltaicsMaterials ChemistryMoietyOptoelectronicsbusinessdescription
The development of new light harvesting materials is a key issue for the progress of the research on organic & hybrid photovoltaics. Here, we report a new class of organic sensitizers based on the bi-fluorenylidene moiety as π-linker within the donor–π-linker–acceptor (D–π–A) scheme. The new dyes are endowed with electron donor and electron acceptor units at strategic positions in order to improve their electronic and light-harvesting properties. The comprehensive study of these compounds through the use of different experimental and theoretical techniques, provides an in-depth understanding of their electronic and photophysical properties, and reveal their interest as photovoltaic materials.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-01-01 |