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RESEARCH PRODUCT

Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer

Iveta VesereMarina PetrovaBaiba SkriveleOksana PetrichenkoAiva PlotnieceYelena GoncharenkoGunars DubursRufus SmitsBrigita Vigante

subject

Pyridinium bromideAtomic force microscopyOrganic ChemistryCationic polymerizationBiochemistryInorganic Chemistrychemistry.chemical_compoundchemistryDynamic light scatteringBromidePolymer chemistryAmphiphileEnvironmental ChemistryOrganic chemistrySelf-assemblyPhysical and Theoretical Chemistry

description

Abstract The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1 H )-pyridone-5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS).

yearjournalcountryeditionlanguage
2011-06-01Journal of Fluorine Chemistry
https://doi.org/10.1016/j.jfluchem.2011.04.008