6533b828fe1ef96bd1287928

RESEARCH PRODUCT

Iron(iii) oxamato-catalyzed epoxidation of alkenes by dioxygen and pivalaldehyde

Rafael RuizYves JournauxBeatriz CerveraIsabel CastroAlly AukaulooJosé R. PedroM. Carmen MuñozIsabel FernándezMaria Triannidis

subject

inorganic chemicalsDioxygenUNESCO::QUÍMICA::Química inorgánicaUNESCO::QUÍMICAorganic chemicalsIronMetals and AlloysIron ; Dioxygen ; Orthophenylenebis ; Catalyst ; PivalaldehydeGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysischemistry.chemical_compoundMonomerchemistryPolymer chemistryMaterials ChemistryCeramics and Compositesheterocyclic compoundsCatalystOrthophenylenebisPivalaldehyde

description

A new iron(III)–carbonato monomeric complex of orthophenylenebis( oxamato) (opba) 1 is synthesized, and spectroscopically and structurally characterized; it is a moderately efficient non-heme catalyst for the aerobic epoxidation of alkenes with co-oxidation of pivalaldehyde. Ruiz Garcia, Rafael, Rafael.Ruiz@uv.es ; Fernandez Picot, Isabel, Isabel.Fernandez@uv.es ; Pedro Llinares, Jose Ramon, Jose.R.Pedro@uv.es

yearjournalcountryeditionlanguage
1997-01-01
http://hdl.handle.net/10550/16766