6533b828fe1ef96bd12883cb

RESEARCH PRODUCT

Ruthenium(II) carbonyl compounds with the 4′-chloro-2,2′:6′,2′′-terpyridine ligand

Matti HaukkaRajendhraprasad Tatikonda

subject

crystal structureCoordination spherechemistry.chemical_elementCrystal structurecarbonyl ligand010402 general chemistry01 natural sciencesResearch Communicationslcsh:ChemistryMetalchemistry.chemical_compoundAtomGeneral Materials Sciencerutheniumta116010405 organic chemistryLigandGeneral Chemistryterpyridine ligandCondensed Matter Physics0104 chemical sciences3. Good healthRutheniumCrystallographylcsh:QD1-999chemistryvisual_artvisual_art.visual_art_mediumTerpyridine

description

The RuII atoms in the crystal structures of two new potential catalyst precursors, [Ru(Tpy-Cl)(CO)2Cl][Ru(CO)3Cl3] and [Ru(Tpy-Cl)(CO)2Cl2] (Tpy-Cl = 4′-chloro 2,2′:6′,2′′-terpyridine-κ3 N), exhibit distorted octa­hedral coordination spheres.

https://doi.org/10.1107/s2056989017003917