6533b828fe1ef96bd1289117

RESEARCH PRODUCT

New Magnetic Thin Film Hybrid Materials Built by the Incorporation of Octanickel(II)-oxamato Clusters Between Clay Mineral Platelets

Luminita Marilena TomaFrancesc LloretDanielle CangussuEmilio PardoRegis Y. N. GenglerPetra Rudolf

subject

MULTIPLET STRUCTURENanostructureFabricationNICKELCationic polymerizationchemistry.chemical_elementNanotechnologyCrystal structureDINICKEL(II) COMPLEXESNanomaterialsMOLECULESNickelchemistryMoleculeCRYSTAL-STRUCTURECOREGeneral Materials ScienceVACANCY LEVELSPhysical and Theoretical ChemistryHybrid materialSPIN-EXCHANGE

description

We report on a new method based on the combination of Langmuir-Schaefer deposition with self-assembly to insert highly anisotropic Ni(8) molecules in a hybrid organic-inorganic nanostructure. Spectroscopic, crystallographic, and magnetic data prove the successful insertion of the guest cationic molecule between templating clay platelets. These results open a new route toward the highly controlled fabrication of tailored functional organic-inorganic nanomaterials.

https://doi.org/10.1021/jz2007929