6533b829fe1ef96bd128ab95

RESEARCH PRODUCT

Spinel-mullite composites with optical properties

Carla ValentínJavier AlarcónM. Sales

subject

Materials scienceSiliconSpinelchemistry.chemical_elementMulliteGeneral Chemistryengineering.materialCondensed Matter PhysicsChlorideElectronic Optical and Magnetic MaterialsAmorphous solidBiomaterialsNickelchemistryMaterials ChemistryCeramics and CompositesmedicineengineeringComposite materialGlass transitionTitaniummedicine.drug

description

The aim of this paper was to study the synthesis and characterization of spinel-containing mullite based materials, using sol-gel techniques. Several gels were prepared, with nominal compositions 3(Al2−2xMx TixO3)·2SiO2 and 3(Al2−xMxO3)·2SiO2, with M=Ni+2 or Co+2 and 0.0≤x≤0.2, by hydrolysis and condensation of mixtures of aluminum, silicon and titanium alkoxides and nickel chloride. Dried gels were homogeneous and displayed a glass transition at around 750°C, which indicated that the system could be described as an amorphous silicoaluminate network.

https://doi.org/10.1007/bf02436953