6533b82bfe1ef96bd128cee8
RESEARCH PRODUCT
Red-light-emitting electrochemical cell using a polypyridyl iridium(III) polymer.
ÁNgela Sastre-santosRubén D. CostaFernando Fernández-lázaroHenk J. BolinkEnrique OrtíJosé L. Rodríguez-redondosubject
chemistry.chemical_classificationMaterials scienceLuminescent MeasurementsLightPolymersIonic bondingchemistry.chemical_elementPolymerElectrochemical TechniquesPhotochemistryIridiumElectrochemical cellInorganic ChemistrychemistryCoordination ComplexesLuminescent MeasurementsIridiumRed lightPhosphorescenceVisible spectrumdescription
A deep-red phosphorescent ionic iridium(III) complex is prepared and incorporated into a polymer. Both the complex (1) and the polymer (2) were used as the single active material in solid-state light-emitting electrochemical cells (LECs). The devices built up using 1 and 2 emit in the deep-red region of the visible spectrum with CIE coordinates x = 0.710; y = 0.283 and x = 0.691; y = 0.289, respectively, making them one of the deepest-red emitting LECs reported. It is the first example of a polymeric LEC incorporating an ionic iridium complex, which exhibits increased stabilities compared with the device based on the small molecular weight complex.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-11-04 | Dalton transactions (Cambridge, England : 2003) |