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RESEARCH PRODUCT
Pressure Effect Studies on the Spin Transition of Microporous 3D Polymer [Fe(pz)Pt(CN)4]
Georgiy LevchenkoGennadiy BukinLudmila BerezhnayaAna B. GasparJosé Antonio Realsubject
chemistry.chemical_classificationCoordination polymerSpin transitionAnalytical chemistry02 engineering and technologyPolymerMicroporous material010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesMagnetic susceptibility0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundParamagnetismAdsorptionchemistryPhysical and Theoretical Chemistry0210 nano-technologyPorositydescription
Pressure effects on the spin transition of the three-dimensional (3D) porous coordination polymer {Fe(pz)[Pt(CN)4]} have been investigated in the interval 105 Pa–1.0 GPa through variable-temperature (10–320 K) magnetic susceptibility measurements and spectroscopic studies in the visible region at room temperature. These studies have disclosed a different behavior of the compound under pressure. In the magnetic experiments, a temperature independent paramagnetic behavior has been observed under 0.4 GPa. In contrast, at room temperature and at 0.8 GPa, a complete HS-to-LS transition has been evidenced. The differences in the magnetic behavior are strongly related with the porous structure of the compound and its capability to adsorb the oil used as pressure transmission media in the magnetic experiments.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-06-27 | Inorganic Chemistry |