ChemInform Abstract: Benzothietes. Versatile Synthons for the Preparation of Heterocycles

6533b82dfe1ef96bd1291298

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ChemInform Abstract: Benzothietes. Versatile Synthons for the Preparation of Heterocycles

subject

chemistry Phosphorus Synthon Heteroatom chemistry.chemical_element General Medicine Ring (chemistry)Nitrogen Combinatorial chemistry Oxygen Sulfur Cycloaddition

description

Abstract Thermal or photochemical ring opening transforms benzo[b]thiete to o-thiobenzoquinonemethide, a highly reactive 8π electron system. Cycloaddition reactions or linear additions with subsequent cyclizations lead to larger heterocyclic rings. A variety of compounds containing sulfur and possibly further heteroatoms like nitrogen, oxygen or phosphorus in normal, medium and large ring systems can be synthesized on this route.

year	journal	country	edition	language
2010-08-03	ChemInform

https://doi.org/10.1002/chin.199728239

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