6533b82dfe1ef96bd1291db4

RESEARCH PRODUCT

Synthesis of iodobiaryls and dibenzofurans by direct coupling at BDD anodes.

Siegfried R. WaldvogelBernd ElslerDieter Schollmeyer

subject

HalogenationChemistryGuaiacolHalogenationOxidation reductionGreen Chemistry TechnologyCatalysisAnodeCatalysischemistry.chemical_compoundPhenolsOrganic chemistryDirect couplingPhenolsGuaiacolPhysical and Theoretical ChemistryDiamondElectrodesOxidation-ReductionDerivative (chemistry)BenzofuransBoron

description

The first direct oxidative phenol-arene cross-coupling reactions of an iodine-containing guaiacol derivative and the possible over-oxidation products of electron-rich phenols are described. Hereby, a "green" and targeted synthesis for dibenzofurans was developed.

10.1039/c4fd00049hhttps://pubmed.ncbi.nlm.nih.gov/25426731