Fluorescent Hg2+ Sensors: Synthesis and Evaluation of a Tren-Based Starburst Molecule Containing Fluorinated 1,2,4-Oxadiazoles.

6533b82dfe1ef96bd1291f3a

RESEARCH PRODUCT

Fluorescent Hg2+ Sensors: Synthesis and Evaluation of a Tren-Based Starburst Molecule Containing Fluorinated 1,2,4-Oxadiazoles.

Silvestre Buscemi Nicolò Vivona Ivana Pibiri Andrea Pace Alessandro Calabrese Alessandro Calabrese Antonio Palumbo-piccionello

subject

Fluorophore Stereochemistry Organic Chemistry Nuclear magnetic resonance spectroscopy Settore CHIM/06 - Chimica Organica Photochemistry Fluorescence Chemical synthesis chemistry.chemical_compound Electron transfer chemistry Proton NMR Molecule Physical and Theoretical Chemistry Selectivity 1 2 4-Oxadiazoles Sensors Electron transfer Fluorinated ligands Mercury

description

A new tren-based starburst molecule containing fluorinated 1,2,4-oxadiazoles as fluorophores has been synthesized and its sensing behavior toward several metal cations has been investigated by UV/Vis, fluorescence, 1 H NMR and 19 F NMR spectroscopy. Selective sensing for Hg 2+ ions through a PET-based mechanism was evidenced, suggesting application as fluorescent sensor for Hg 2+ of the off-on type.

year	journal	country	edition	language
2010-07-16

10.1002/ejoc.201000763 http://hdl.handle.net/10447/52094

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