6533b82dfe1ef96bd12920cd

RESEARCH PRODUCT

An easy access to fused chromanones via rhodium catalyzed oxidative coupling of salicylaldehydes with heterobicyclic olefins

Ajesh VijayanT. V. BaijuE. JijyPraveen PrakashM. ShimiNayana JosephPetri PihkoSunil VarugheseK. V. Radhakrishnan

subject

diazabicyclic olefinschromanonerhodium catalyzedsalicylaldehydeurea derived bicyclic olefins

description

Herein we describe a detailed study on the rhodium catalyzed oxidative coupling of salicylaldehydes with heterobicyclic olefins such as diazabicyclic olefins and urea-derived bicyclic olefins. The developed method provides an ideal route to fused chromanone systems in a single synthetic step. Moreover, the scope of this methodology was extended to different oxa/aza-bridged bicyclic urea derivatives. peerReviewed

http://urn.fi/URN:NBN:fi:jyu-201607013429