6533b82efe1ef96bd1292848

RESEARCH PRODUCT

Connections Between Theory and Experiment for Gold and Silver Nanoclusters.

Hannu HäkkinenK. L. Dimuthu M. WeerawardeneChristine M. Aikens

subject

Materials scienceNanotechnology02 engineering and technologyPhysical and Theoretical Chemistry010402 general chemistry021001 nanoscience & nanotechnology0210 nano-technology01 natural sciences0104 chemical sciencesNanoclusters

description

Ligand-stabilized gold and silver nanoparticles are of tremendous current interest in sensing, catalysis, and energy applications. Experimental and theoretical studies have closely interacted to elucidate properties such as the geometric and electronic structures of these fascinating systems. In this review, the interplay between theory and experiment is described; areas such as optical absorption and doping, where the theory–experiment connections are well established, are discussed in detail; and the current status of these connections in newer fields of study, such as luminescence, transient absorption, and the effects of solvent and the surrounding environment, are highlighted. Close communication between theory and experiment has been extremely valuable for developing an understanding of these nanocluster systems in the past decade and will undoubtedly continue to play a major role in future years. Expected final online publication date for the Annual Review of Physical Chemistry Volume 69 is April 2...

10.1146/annurev-physchem-052516-050932https://pubmed.ncbi.nlm.nih.gov/29490202