6533b82efe1ef96bd1293afe

RESEARCH PRODUCT

Spektroskopische analyse mehrfacher methacrylsäureester von oligo[(2-hydroxy-1,3-phenylen)methylen]en mittels UV-, IR-, 1H NMR- und massenspektren

Hermann KämmererJiri PachtaJürgen Ritz

subject

Homologous serieschemistry.chemical_compoundchemistryMethacrylic acidPolymer chemistryMass spectrumProton NMRInfrared spectroscopyMoleculeMethyleneAbsorption (chemistry)

description

The structures of two homologous series of oligo[(2-hydroxy-1,3-phenylene)methylene]s completely esterified with methacrylic acid, were spectroscopically analysed. The molar decadal absorption coefficients of ultraviolet absorption maxima of the two homologous series confirm Hunter's relation. The vinylidene, ester, and substitution bands of the infrared spectra as well as the mass spectra agree with the accepted structures. The 1H NMR spectra permit to differentiate between exterior and interior groups of the molecules.

https://doi.org/10.1002/macp.1977.021780502