Theoretical search for very short metal-actinide bonds: NUIr and isoelectronic systems.

6533b82efe1ef96bd1293c1e

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Theoretical search for very short metal-actinide bonds: NUIr and isoelectronic systems.

subject

010405 organic chemistry Chemistry Isolobal principle General Chemistry General Medicine Actinide 010402 general chemistry Iridium Multiple bonds 01 natural sciences Catalysis Computer chemistry 0104 chemical sciences Metal Crystallography Density functional calculations visual_art Atom ddc:540 visual_art.visual_art_medium Physical chemistry Uranium Multiple bonding

description

, respectively. These analogues provide anexample ofthe isolobal principle, now without any outsideligands onthePt atom,asituation describedasits “autogenicisolobality”. These systems have multiple C Pt bonds. Theisolobal principle of Hoffmann refers to the similar chemicalbehaviorofansphybridandametalatomwithligands,-ML

year	journal	country	edition	language
2004-03-12	Angewandte Chemie (International ed. in English)

10.1002/anie.200353261 https://pubmed.ncbi.nlm.nih.gov/15022237

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