6533b82efe1ef96bd129457f
RESEARCH PRODUCT
Electron impact mass spectra of chlorinated methyl propanoates
Ilpo O.o. Korhonensubject
ChemistryPolyatomic ionAnalytical chemistryBiochemistrySpectral lineIonFragmentation (mass spectrometry)DeuteriumMass spectrumMolecular MedicineMoleculePhysical chemistryInstrumentationSpectroscopyElectron ionizationdescription
The mass spectral fragmentations of all eleven chlorinated methyl propanoates have been studied. Deuterium labelling and metastable ion analysis were used to elucidate the fragmentation mechanism. The molecular ion peaks of all compounds are small, except methyl 3,3-dichloropanoate (38%). In most cases α-cleavage gives the base peak [COOCH3]+, and the loss of a chlorine atom from the molecular ion is characteristic of the 3-chloro, 3,3-dichloro and 3,3,3-trichloro compounds. Metastable ions showed the losses of small neutral molecules such as CH3OH, CH2CO, CO2 and CO from the [MCl]+ ion. α-Cleavage and the loss of Cl˙ gives an intense [MCOOCH3Cl]+˙ peak, which is the base peak in the spectra of the 2,3-dichloro and 2,3,3-trichloro compounds.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1982-10-01 | Organic Mass Spectrometry |