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RESEARCH PRODUCT

Luminescence of biexcitons in silver halide crystals

Donats MillersVladimir PankratovLarisa Grigorjeva

subject

PhotoluminescenceSilver halideExcitonBinding energyBiophysicsGeneral ChemistryCondensed Matter PhysicsBiochemistryAtomic and Molecular Physics and Opticschemistry.chemical_compoundchemistryAbsorption edgeFrenkel defectAtomic physicsLuminescenceBiexciton

description

Abstract As it is known from Urbach rule, free excitons defining the fundamental absorption edge in AgBr 1 − x Cl x (0 ⩽ x ⩽ 1). The process of primary Frenkel defect creation which involves free exciton states even in AgCl and biexciton creation in AgCl are discussed. The fast luminescence band at ≈3.0 eV observed in AgCl under high-density pulsed electron beam and laser excitation has been studied. It is shown that its intensity is a non-linear function of the excitation density. We suggest that the fast luminescence comes from biexcitons; binding energies of such biexcitons in AgBr 1 − x Cl x (0 ⩽ x ⩽ 1) are estimated.

https://doi.org/10.1016/s0022-2313(97)00270-6