6533b82ffe1ef96bd1295e05

RESEARCH PRODUCT

Argon-broadened line parameters in the nu3 band of 12CH4

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International audience; Prompted by improved measurements of collisional line shapes in the nu3 band P, Q and R branches of 12CH4, we have performed semi-classical line broadening calculations for methane perturbed by argon. We have used the theoretical approach developed by Robert and Bonamy as an extension of the well-known Anderson-Tsao-Curnutte theory. The semi-classical theory as reformulated here is shown to fully account for the tetrahedral symmetry of methane type molecules. The variation of argon-broadened linewidth coefficients in the nu3 band of 12CH4 with the branch, J, symmetry and energy level fine structure is discussed.